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Summary

Realising a sustainable hydrogen economy requires breakthroughs in the production and storage of hydrogen. Focussing on research areas that have been singled out as areas that might see such breakthroughs, the network aims to devise a tandem cell which can photoelectrochemically convert solar energy to energy in hydrogen with an efficiency greater than 10%, and to find the best possible complex-metal hydride hydrogen storage system for on-board storage in automobiles.

Summary

The Hydrogen research program is aimed at achieving breakthrough solutions for the production and storage of hydrogen. If successful, the research can contribute to an accelerated introduction of the hydrogen economy, the realisation of which is a stated EU policy goal. The research will also lead to long-term innovation and the development of new knowledge. Success will contribute to a strengthening of the competitiveness of Europe and will foster economic growth.

Training programme and transfer of knowledge activities

The network will train 10 ESRs (30 fte years) and 6 ERs (11.5 fte years) in research on production and storage of hydrogen. Training young people in research aimed at realising the hydrogen exconomy is a stated European policy goal. Training is provided in the scientific areas that are associated with the research objectives, with an emphasis on interdisciplinarity and intersectorial aspects. It will be based on personalized career development plans to provide the ESRs and ERs with balanced sets of skills and advanced knowledge at the leading edge of science and technology.

The importance of research for the hydrogen economy

The importance of research aimed at enabling the introduction of hydrogen as a clean fuel can hardly be overstated, and the introduction of the hydrogen economy is a stated policy goal of the EU [1, 2]. First, fossile fuels reserves are limited. Present estimates are that, at the current usage rate, oil will run out in 40 years, natural gas in 60 years, and coal in 200 years [3]. Second, scientific evidence is accumulating that the emission of CO2 that accompanies fossile fuel use is leading to global warming.

Current methods for production

The current commercial process for producing hydrogen is steam reforming of natural gas. Hydrogen can also be produced from coal using gasification technology. Both methods have as disadvantages that they result in CO2 emission (even if CO2 could be sequestered, the safety of sequestration techniques is presently under discussion), that the availability of natural gas and coal is limited, and a disadvantage of natural gas is that most of it is present in non-EU, sometimes unstable countries, with consequences for energy security [6]. Other methods of producing hydrogen use nuclear energy, electricity from solar cells or from wind energy, biomass (which cannot be grown in sufficient quantities to fulfill world energy needs), and photobiological and photoelectrochemical processes [6]. Photoelectrochemical hydrogen production is mentioned in both a recent energy technology analysis of the International Energy Agency (IEA) [6] and in a recent report of the National Research Council and the National Academy of Engineering of the US (NRC/NAE report) [5] as an important research area where the kind of technological and conceptual breakthroughs required for the hydrogen economy are possible, and the network will focus its research on production of hydrogen exclusively on this production technique.

Experiments & theory

There is not enough space to list all the methods that will be used in the research programme; we will therefore only mention the more important ones in this Section. In the theoretical research, we will use, for instance, density functional theory (DFT), a new QM-MM (Quantum Mechanics-Molecular Mechanics) approach, the time-dependent wave packet (TDWP) method, and quantum transition state theory (QTST).

State of the art research

Hydrogen can be produced efficiently and cheaply using a tandem cell [16, 17]. This device (see Figure below) connects a photoelectrochemical cell to a Grätzel solar cell. The Grätzel cell converts energy in red light to electricity, providing the small extra bias to drive oxygen production over the metaloxide electrode which absorbs blue light in the photoelectrochemical cell. Hydrogen Solar, which aims to bring the tandem cell to the market, reports an efficiency of 8% for a tandem cell based on a WO3 photoanode in the photoelectrochemical cell [18].

Sunday 14 Nov
15:00 - 18:00 Registration
18:00 Dinner
20:00 - 22:00 Reception
Friday 19 Nov
08:00 Breakfast
 

Session: Network talks III

09:00 - 09:20 Lorand Romanszki (Chalmers): Porous templates to study hydrogen storage by quartz crystal microbalance
09:20 - 09:40 Florian Le Formal (EPFL):Hematite thin films for solar driven watersplitting
09:40 - 10:00 Ewa Banach (Shell): AlxHy<
Thursday 18 Nov
08:00 Breakfast
 

Session: Storage III

09:00 - 09:40 Maximilian Fichtner (Karlsruhe Institute of Technology): Kinetic and Thermodynamic Properties of Nanoconfined Materials for Energy Storage
09:40 - 10:05 Raghu Baktha (Sandia National Laboratories, USA): Investigation of metal hydride nanoparticles templated in metal organic frameworks
10:05 - 10: